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3.7 f. Welding of volcanic glasses: Quantification via viscosity-temperature-H2O relationship for Teide phonolites (D. Giordano and D.B. Dingwell, in collaboration with C. Romano/Rome and J. Marti/Barcelona)

The welding of volcanic glasses is a subject of great importance in modern volcanology because the physical and chemical properties of the volcanic sequence are strongly influenced by the welding process, yielding consequences for their alteration, for volcanic edifice stability, and for resultant hydrology. Welding is essentially a stress relaxation phenomenon that may be accompanied by significant diffusion (chiefly of water), and surface modification via resorption of bubbles and possibly crystal growth. The kinetics of welding is therefore essentially controlled by an interplay of three variables, load, viscosity and time. The loading conditions are usually relatively easy to estimate, based on stratigraphy. Timescales can sometimes be accessed via geospeedometry on welded sequences. Estimation of the viscosity depends essentially on three variables, two of which, chemical composition and water content, can often be measured and the third, temperature, which must be estimated.

Quantification of welding temperature estimates relies on an accurate knowledge of the relationship between temperature, composition, water content and viscosity. The continuity and constancy of chemical composition for certain volcanic fields that exhibit a very wide range of welding textures, makes it worthwhile to perform detailed viscometric investigations of the melts as a function of water content and temperature. An example of such a field is formed by the pyroclastic phonolitic products of Teide volcano. We have determined the viscosities of hydrous phonolitic melts in the range of viscosity, water content and temperature very near to that where welding must occur for these melts. These data are presented in Fig. 3.7-9. Also included in Fig. 3.7-9 are the results of a fit of the the data which has been parameterised to an analytical function of water content and temperature. The results show the remarkably low temperatures to which the welding of melts, just above the glass transition, are possible for phonolitic compositions (i.e., less than 645°C). Work is currently in progress to compare the efficiency of welding to be expected in calcalkaline versus phonolitic volcanic piles under comparable conditions of eruptive temperature and loading.

Fig. 3.7-9: Viscosity-temperature relationships for phonolitic melts of variable water content. The variation of viscosity with water content at constant temperature yields a strongly nonlinear relationship similar in shape to that observed for calcalkaline rhyolite but shifted to much lower viscosities. The depressed glass transition temperatures that can be inferred from this figure mean that welding and potentially rheomorphic remobilization of phonolitic air-fall and lavas should be much more widespread than in calcalkaline rhyolites erupted at similar temperatures.

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